I’ve been messing around with loads for .38 S&W (NOT .38 Special, it’s a different cartridge) and trying to make sense of the contradictory and sometimes unhelpful advice from Americans on the subject.
Anyway, it turns out 3.2gr of Unique behind a 145gr LRN projectile does not work well at all out of a Webley Mk IV. It goes bang, but is incredibly inaccurate - despite being a promising load “on screen”.
Might try a heavier cartridge next time - I hear 158gr projectiles can work quite well.
You should find somewhere that shoots Metallic Silhouette and get that .45 endorsement. Then get a Mk VI Webley in .455. Then use it to shoot the matches, and have fun while the people with customised guns still don’t score much better (or better at all) than you.